The Guareschi Pyridine Scaffold as a Valuable Platform for the Identification of Selective PI3K Inhibitors.

نویسندگان

  • Ubaldina Galli
  • Elisa Ciraolo
  • Alberto Massarotti
  • Jean Piero Margaria
  • Giovanni Sorba
  • Emilio Hirsch
  • Gian Cesare Tron
چکیده

A novel series of 4-aryl-3-cyano-2-(3-hydroxyphenyl)-6-morpholino-pyridines have been designed as potential phosphatidylinositol-3-kinase (PI3K) inhibitors. The compounds have been synthesized using the Guareschi reaction to prepare the key 4-aryl-3-cyano-2,6-dihydroxypyridine intermediate. A different selectivity according to the nature of the aryl group has been observed. Compound 9b is a selective inhibitor against the PI3Kα isoform, maintaining a good inhibitory activity. Docking studies were also performed in order to rationalize its profile of selectivity.

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عنوان ژورنال:
  • Molecules

دوره 20 9  شماره 

صفحات  -

تاریخ انتشار 2015